http://arxiv.org/abs/2305.05787
Reproduction experiments of radial pyroxene (RP) chondrules were carried out using Ar-$\mathrm{H_2}$ or Ar gas-jet levitation system in a reduced atmosphere in order to simulate chondrule formation in the protoplanetary disk. The experiments reproduced RP-chondrule texture, consisting of sets of thin pyroxene crystals and mesostasis glass between crystals. However, iron partition coefficients between pyroxene and glassy mesostasis ($\rm{D_{Fe}}$ = Fe mol$\rm{\%{pyroxene}}$ / Fe mol$\rm{\%{mesostasis}}$) in natural RP chondrules were much higher than that in experimentally reproduced RP chondrules. The high $\rm{D_{Fe}}$ in natural RP chondrules suggest that iron was removed from the mesostasis melt at high temperatures after the crystal growth of pyroxene. We found that many small iron-metal inclusions had formed in the mesostasis glass, indicating that FeO in the high-temperature melt of mesostasis was reduced to metallic iron, and iron in the mesostasis was diffused into newly-formed metal inclusions. The formation of the iron-metal inclusions in the mesostasis was reproduced by our experiments in a reduced atmosphere, confirming that $\rm{D_{Fe}}$ in natural RP chondrules increased after the crystal growth of radial pyroxenes. Therefore, $\rm{D_{Fe}}$ of RP chondrules can be an indicator to constrain cooling rates and redox states during the chondrule formation.
K. Watanabe, T. Nakamura and T. Morita
Thu, 11 May 23
24/55
Comments: 38 pages, 4 figures, 10 tables, in review in ApJ